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We study the influence of Fe-substitution on the structure of small alumina clusters using gas phase vibrational spectroscopy in combination with density functional theory.

Infrared Photodissociation Spectroscopy of (Al2O3)2–5FeO+: Influence of Fe-Substitution on Small Alumina Clusters
Sreekanta Debnath, Marcel Jorewitz, Knut R. Asmis, Fabian Müller, Julius B. Stückrath, Florian A. Bischoff, Joachim Sauer

 

Phys. Chem. Chem. Phys. 2022, 24, 20913 
doi.org/10.1039/D2CP02938C

From the themed collection: 
Stability and properties of new-generation metal and metal-oxide clusters down to subnanometer scale