Publikationen

• M. Reimann, H. Kohlmann, S. F. Matar, R. Pöttgen, Ternary magnesium gallides – synthesis, crystal chemistry and properties of CaMgGa, SrMgGa, BaMgGa and YbMgGa, Z. Anorg. Allg. Chem. 2023, 649, e202200361; doi.org/10.1002/zaac.202200361.
• H. Kohlmann, L. Dorsch, Hydrogen storage materials, Chapter 5.4 in: R. Pöttgen, T. Jüstel, C. A. Strassert (Eds.), Applied Inorganic Chemistry, Vol. 2, de Gruyter, Berlin, 2023, 39-53; doi.org/10.1515/9783110798890.

• S. Keilholz, R. Paul, L. Y. Dorsch, H. Kohlmann, In Situ X-ray Diffraction Studies on the Reduction of V₂O₅ and WO₃ by Using Hydrogen,Chem. Eur. J. 2023, 29, e202203932; doi.org/10.1002/chem.202203932

• S. Keilholz, H. Uhlenhut, A. Gabke, M Garcia-Schollenbruch, H. Kohlmann, In situ studies on the industrial production process for molybdenum dioxide, MoO₂,Z. Anorg. Allg. Chem. 2023, 649, e202300111; doi.org/10.1002/zaac.202300111

• O. Yu. Vekilova, D. C. Beyer, S. Bhat, R. Farla, V. Baran, S. I. Simak, H. Kohlmann, U. Häussermann, K. Spektor, Formation and Polymorphism of Semiconducting K₂SiH₆ and Strategy for Metallization, Inorg. Chem. 2023, 62, 8093–8100; doi.org/10.1021/acs.inorgchem.2c04370

• K. Spektor, H. Kohlmann, D. Druzhbin, W. A. Crichton, S. Bhat, S. I. Simak, O. Yu. Vekilova, U. Häussermann, Hypervalent hydridosilicate in the Na–Si–H system,Front. Chem. (Lausanne, Switz.) 2023, 11, 1251774; doi.org/10.3389/fchem.2023.1251774

• R. Finger, T. C. Hansen, H. Kohlmann, A double-walled sapphire single-crystal gas-pressure cell (type III) for in situ neutron diffraction, J. Appl. Crystallogr. 2022, 55, 67–73; doi.org/10.1107/S1600576721012048.

• N. Zapp, H. Kohlmann, Ternary rare-earth hydride oxides: stability in air and potential use as precursors for the synthesis of materials, Z. Naturforsch., B: Chem. Sci. 2022, 77, 67–73; doi.org/10.1515/znb-2021-0189.

• H. Kohlmann, Rotationally ordered ammonium cations in the crystal structure of (NH₄)₂OsBr₆, Z. Anorg. Allg. Chem. 2022, 648, e202100375; doi.org/10.1002/zaac.202100375.

• C. Pflug, D. Rudolph, T. Schleid, H. Kohlmann, Hydrogenation reaction pathways and crystal structures of La₂H₂Se, La₂H₃Se and La₂H₄Se, Eur. J. Inorg. Chem. 2022, e202101095; doi.org/10.1002/ejic.202101095.

• S. Keilholz, H. Kohlmann, H. Uhlenhut, A. Gabke, M Garcia-Schollenbruch, In Situ X-ray Diffraction Studies on the Production Process of Molybdenum, Inorg. Chem. 2022, 61, 10126–10132; doi.org/10.1021/acs.inorgchem.2c01226.

• S. Keilholz, H. Kohlmann, H. Uhlenhut, A. Gabke, M Garcia-Schollenbruch, In Situ X-ray diffraction studies on the production process of rhenium, Z. Anorg. Allg. Chem. 2022, 648, e202200232; doi.org/10.1002/zaac.202200232.

• J.-L. Hoslauer, N. Zapp, H. E. Fischer, D. Rudolph, H. Kohlmann, T. Schleid, Synthesis and Crystal-Structure Analysis of the K₂NiF₄-Type Hydride Oxides LiLnEuH_2–xO₂ (Ln = La, Ce, Pr, Nd, Sm) and LiEu₂H₃O by Neutron and X-Ray Diffraction, Z. Anorg. Allg. Chem. 2022, 648, e202200266; doi.org/10.1002/zaac.202200266.

• N. Zapp, F. Oehler, M. Bertmer, H. Auer, D. Sheptyakov, C. Ritter, H. Kohlmann, Aliovalent anion substitution as a design concept for heteroanionic Ruddlesden–Popper hydrides, Chem. Commun. 2022, 58, 12971–12974; doi.org/10.1039/D2CC04356D.

• H. Mohammadi, R. Mendes Da Silva, A. Zeidler, L. V. D. Gammond, F. Gehlhaar, M. de Oliveira Jr., H. Damasceno, H. Eckert, R. E. Youngman, B. G. Aitken, H. E. Fischer, H. Kohlmann, L. Cormier, C. J. Benmore, P. S. Salmon, Structure of diopside, enstatite and magnesium aluminosilicate glasses: A joint approach using neutron and x-ray diraction and solid-state NMR, J. Chem. Phys. 2022, 157, 214503; doi.org/10.1063/5.0125879.

• A. Götze, S. C. Stevenson, T. C. Hansen, H. Kohlmann, Hydrogen induced order-disorder effects in FePd₃, Crystals 2022, 12, 1704; doi.org/10.3390/cryst12121704.

• J. Möllmer, H. Uhlig, M. Lange, J. Hofmann, A. L. Kolesnikov, Y. A. Budkov, A. Götze, H. Kohlmann, Thermodynamics of hydrogen sorption in MgPd₂, J. Alloys Compd. 2021, 859, 157782; doi.org/10.1016/j.jallcom.2020.157782.

• S. Weber, S. Schäfer, M. Saccoccio, K. Seidel, H. Kohlmann, R. Gläser, S. A. Schunk, Mayenite-based electride C12A7e^–: an innovative synthetic method via plasma arc melting, Mater. Chem. Front. 2021, 5, 1301–1314; doi.org/10.1039/D0QM00688B.

• N. Zapp, D. Sheptyakov, A. Franz, H. Kohlmann, HoHO – a Paramagnetic Air-Resistant Ionic Hydride with Ordered Anions, Inorg. Chem. 2021, 60, 3972–3979; doi.org/10.1021/acs.inorgchem.0c03822.

• R. Finger, N. Kurtzemann, T. C. Hansen, H. Kohlmann, Design and use of a sapphire single-crystal gas-pressure cell for in situ neutron diffraction, J. Appl. Crystallogr. 2021, 54, 839–846; doi.org/10.1107/S1600576721002685.

• S. Weber, S. Schäfer, M. Saccoccio, N. Ortner, M. Bertmer, K. Seidel, S. Behrendts, M. Lerch, R. Gläser, H. Kohlmann, S. A. Schunk, Mayenite-based electride C12A7e^-: A Reactivity and Stability Study, Catalysis 2021, 11, 334; doi.org/10.3390/catal11030334.

• N. Zapp, D. Sheptyakov, H. Kohlmann, Computational Chemistry-Guided Syntheses and Crystal Structures of the Heavier Lanthanide Hydride Oxides DyHO, ErHO, and LuHO, Crystals 2021, 11, 750; doi.org/10.3390/cryst11070750.

• R. Finger, T. C. Hansen, H. Kohlmann, Validation of a Sapphire Gas-Pressure Cell for Real-Time In Situ Neutron Diffraction Studies of Hydrogenation Reactions, Quantum Beam Sci. 2021, 5, 22; doi.org/10.3390/qubs5030022.

• N. Zapp, H. E. Fischer, H. Kohlmann, From SmOF to SmH_0.78OF_0.22: H/F substitution in oxide fluorides as synthesis route to new heteroanionic compounds, Inorg. Chem. 2021, 60, 17775–17782; doi.org/10.1021/acs.inorgchem.1c02402.

• R. Finger, T. C. Hansen, H. Kohlmann, Simultaneous neutron powder diffraction and Raman spectroscopy – an approach of combining two complementary techniques, Z. Kristallogr. 2021, 236, 325–328; doi.org/10.1515/zkri-2021-2051.

• R. Finger, M. Widenmeyer, T. C. Hansen, D. Wallacher, S. Savvin, M. Bertmer, A. Weidenkaff, H. Kohlmann, Effects of Cr Doping and Water Content on the Crystal Structure Transitions of Ba₂In₂O₅, Crystals 2021, 11, 1548; doi.org/10.3390/cryst11121548.

• E. A. Stroganova, S. M. Kazakov, N. M. Efimov, V. N. Khrustalev, S. Keilholz, A. Götze, H. Kohlmann, A. N. Kuznetsov, Nickel–p-block metal mixed chalcogenides based on Cu₃Au-type fragments: iodine-assisted synthesis as a way of obtaining new structures, Dalton Trans. 2020, 49, 15081–15094, doi: 10.1039/d0dt03082a
• H. Kohlmann, The crystal structure of ZrCr₂D_≈4 at 50 K ≤ T ≤ 200 K, Z. Naturforsch., B: Chem. Sci. 2020, 75, 969-973, doi: 10.1515/znb-2020-0150
• H. Kohlmann, Hydrogen order in hydrides of Laves phases, Z. Kristallogr., 2020, 235, 319-332, doi: 10.1515/zkri-2020-0043
• A. Werwein, H. Kohlmann, Synthesis and Crystal Structure of BaLaSi₂H_0.80(1), Z. Anorg. Allg. Chem. 2020, 646, 1227-1230, doi: 10.1002/zaac.202000152
• S. C. Stevenson, A. Götze, H. Kohlmann, Synthesis and Crystal Structure of SnPd₃D_0.138(7), Z. Anorg. Allg. Chem. 2020, 646, 1490-1493, doi: 10.1002/zaac.202000104
• C. J. Ridley, N. P. Funnel, C. L. Bull, H. Kohlmann, Neutron diffraction study of the α- to β-phase transition in BaD₂ under high pressure, Solid State Commun. 2020, 318, 113965, doi: 10.1016/j.ssc.2020.113965
• H. Kohlmann, Solid-gas reactions in synthetic chemistry - what can we learn from reaction pathways?, Russ. Chem. Rev. 2020, 89, 275-280
• H. Kohlmann, A. Rauchmaul, S. Keilholz, A. Franz, Crystal structure and thermal behavior of SbC₂O₄OH and SbC₂O₄OD, Inorganics 2020, 8, 21, doi: 10.3390/inorganics8030021
• F. Gehlhaar, S. Keilholz, H. Kohlmann, In situ X-ray powder diffraction study of the reactions of CrO2 and TlPd₃O₄ with hydrogen, Z. Anorg. Allg. Chem. 2020, 646, in print, doi: 10.1002/zaac.201900323
• C. Pflug, H. Kohlmann, Structural Distortion in Perovskite Type KCaH_3-xF_x (0.54 ≤ x ≤ 3), Z. Anorg. Allg. Chem. 2020, 646, 175-179, doi: 10.1002/zaac.201900309
• H. Kohlmann, Rare earth metal based hydride materials, in: R. Pöttgen, T. Jüstel, C. A. Strassert (Eds.), Rare Earth Chemistry, de Gruyter, Berlin, 2020

• A. Werwein, T. C. Hansen, H. Kohlmann, Size Matters: New Zintl Phase Hydrides of REGa (RE = Y, La, Tm) and RESi (RE = Y, Er, Tm) with Large and Small Cations, Crystals 2019, 9, 600; doi: 10.3390/cryst9110600
• N. Zapp, H. Auer, H. Kohlmann, YHO, an Air-Stable Ionic Hydride, Inorg. Chem. 2019, 58, doi: 0.1021/acs.inorgchem.9b02308
• H. Kohlmann, Looking into the Black Box of Solid-State Synthesis (Minireview, Very Important Paper), Eur. J. Inorg. Chem. 2019, 4174-4180, doi: 10.1002/ejic.201900733
• H. Auer, F. Yang, H. Y. Playford, T. C. Hansen, A. Franz, H. Kohlmann, Covalent Si-H bonds in the Zintl phase hydride CaSiH_1+x (x ≤ 1/3), Inorganics 2019, 7, 106, doi: 10.3390/inorganics7090106
• L. Chen, P. Cheng, Z. Zhang, L. He, Y. Jiang, G. Li, X. Jing, Y. Qin, M. Yin, T.-S. Chan, B. Hong, S. Tao, W. Chu, Z. Zhao, H. Ni, H. Kohlmann, O. Oeckler, Reduced local symmetry in lithium compound Li₂SrSiO₄ distinguished by a Eu³⁺ spectroscopy probe, Adv. Sci. (Weinheim, Ger.)  2019, 6, 1802126
• R. Guehne, H. Auer, H. Kohlmann, J. Haase, M. Bertmer, Determination of element-deuterium bond lengths in Zintl phase deuterides by ²H-NMR, Phys. Chem. Chem. Phys. 2019, 21, 10594-10602 , doi: 10.1039/C9CP00292H
• A. Werwein, C. Benndorf, M. Bertmer, A. Franz, O. Oeckler, H. Kohlmann, Hydrogenation Properties of LnAl₂ (Ln = La, Eu, Yb), LaGa₂, LaSi₂ and the Crystal Structure of LaGa₂H_0.71(2), Crystals 2019, 9, 193, doi: 10.3390/cryst9040193
• H. Kohlmann, The crystal structure of cubic C-type samarium sesquioxide, Sm₂O₃, Z. Naturforsch., B: Chem. Sci. 2019, 74, 433-435, doi: 10.1515/znb-2019-0042
• H. Auer, R. Nedumkandathil, U. Häussermann, H. Kohlmann, The Hydrogenation of the Zintl Phase NdGa studied by in situ Neutron Diffraction, Z. Anorg. Allg. Chem. 2019, 645, 175-181, doi: 10.1002/zaac.201800459

Zu finden unter orcid.org/0000-0002-8873-525X.

2021

• Nicolas Zapp, Dissertation, Universität Leipzig, 2021.
  Rare Earth Heteroanionic Hydrides with Secondary O^2˗-, F^˗-, and N^3˗-Ions Related to the CaF₂- and K₂NiF₄-Structure Types
  https://nbn-resolving.org/urn:nbn:de:bsz:15-qucosa2-784931

2019

• Anton Werwein, Dissertation, Universität Leipzig, 2019.
  Hydrogenation of rare earth containing intermetallics with FeB, CrB and AlB₂ structure type

2018

• André Götze, Dissertation, Universität Leipzig, 2018.
  Structure-Directing Influence of Hydrogen on the Formation of Hydrides of Palladium and Rhodium Compounds Based on In Situ Studies
  http://nbn-resolving.de/urn:nbn:de:bsz:15-qucosa2-324205
• Henry Auer, Dissertation, Universität Leipzig, 2018.
  In Situ and Ex Situ Hydrogenation Studies of Zintl Phases Containing Tetrelides or Gallium
  http://nbn-resolving.de/urn:nbn:de:bsz:15-qucosa2-318350

2017

• Andreas Walgenbach, Dissertation, Universität des Saarlandes, 2018.
  Neue molekulare Aluminiumhydride und deren Anwendung
  https://d-nb.info/1132133734/34

2016

• Afua Serwah, Dissertation, Fresenius Medical Care, St. Wendel, 2016.
  Untersuchungen zur Metallionenbestimmung von Natrium, Kalium, Magnesium und Calcium als prozessanalytische Methode in der Arzneimittelherstellung

2014

• Patrick Wenderoth, Dissertation, Universität des Saarlandes, 2014.
  Untersuchungen zur Hydridbildung von Zintl-Phasen der Erdalkalimetalle mit Aluminium, Gallium und Silicium
  https://d-nb.info/1054055076/34
• Nathalie Kunkel, Dissertation, Universität des Saarlandes, 2014.
  Luminescent Metal Hydrides Containing Europium(II) and Hydrogenation Studies of Ytterbium and Li_xSr_1-xAlSi
  https://d-nb.info/1054055041/34
• Christian Reichert, Dissertation, Universität des Saarlandes, 2014.
  Untersuchungen zu Synthese und Hydrierverhalten von Verbindungen der Triele (B, Al, Ga) mit Lithium und Kalium
  https://d-nb.info/1053982534/34